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Water
and Wastewater Analysis
|
The following
test methods are utilized for the analysis of water and wasterwater samples
according to procedures described in "Methods for Chemical Analysis
of Water and Wastes", 1983, and "Standard Methods for the Evaluation
of Water and Wastewater", 1989.
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| |
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ANALYSIS
|
METHOD
|
| Acidity
(Titrimetric) |
305.1 |
| Alkalinity
(Titrimetric) |
310.1 |
| Ammonia
Nitrogen (Spectrophotometric, Titrimetric) |
350.2 |
| Biochemical
Oxygen Demand (BOD) |
405.1 |
| Bromide
(Titrimetric/Chromatographic) |
320.1/300.0 |
| Chemical
Oxygen Demand (Spectrophotometric) |
410.4 |
| Chloride
(Titrimetric/Chromatographic) |
325.3/300.0 |
| Chlorine,
Residual (Titrimetric) |
330.5 |
| Chromium,
Hexavalent |
3500CrD |
| Coliform,
Fecal |
9222D |
| Coliform,
Total |
9222B |
| Color
(Colorimetric, Pt-Co) |
110.2 |
| Conductivity
(Specific Conductance) |
120.1 |
| Cyanide,
Total (Spectrophotometric) |
335.2 |
| Dissolved
Oxygen |
360.1 |
| Fluoride
(Potentiometric/Chromatographic) |
340.2/300.0 |
| Hardness,
Total (Titrimetric) |
130.2 |
| Iodine
(Titrimetric) |
345.1 |
| Metals
(Flame AA and ICP) |
200 Series |
| Metals
(Vapor AA) |
|
| Metals
(Graphite Furnace) |
|
| Nitrogen,
Nitrate (Spectrophotometric/Chromatographic) |
352.1/300.0 |
| Nitrogen,
Nitrite (Spectrophotmetric/Chromatographic |
354.1/300.0 |
| Nitrogen,
Nitrate/Nitrite (Spectrophotometric/Chromatographic |
353.3/300.0 |
| Oil and
Grease, Total Recoverable |
1664 |
| pH (Electrometric) |
150.1 |
| Phenols,
Total Recoverable |
420.1 |
| Phosphorus,
all forms |
365.2/200.7/300.0 |
| Settleable
Matter |
160.5 |
| Solids:
Dissolved (TDS) |
160.1 |
| Suspended
(TSS) |
160.2 |
| Total
(TS) |
160.3 |
| Volatile
(VSS) |
160.4 |
| Sulfate
(Turbidimetric/Chromatographic) |
375.4/300.0 |
| Sulfide
(Titrimetric) |
376.1 |
| Sulfite
(Titrimetric) |
377.1 |
| Surfactant
(MBAS) |
5540C |
| Temperature |
170.1 |
| Total
Kjeldahl Nitrogen (TKN) |
351.3 |
| Total
Organic Carbon (TOC) |
415.1
|
| Total
Organic Halide (TOX) |
9020B |
| Total
Petroleum Hydrocarbons - Carbon (Gravimetric) |
5520B/F |
| Turbidity
(Nephelometric) |
180.1 |
|
|
All other
analytical methods employed will be based on the most recently promulgated
methods in the FEDERAL REGISTER.
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Hazardous
Waste (RCRA) Evaluations
|
|
All methods are described
in "Test Methods for the Evaluation of Solid Waste," 1994
(SW-846) 3rd Ed.
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| |
|
| TCLP
Analysis |
METHOD
|
| Metals
by ICP/AA |
6010A/7470A |
| Pesticides/Herbicides
by GC/ECD |
8081/8151 |
| Semi-Volatile
Organics by GC/MS |
8270B |
| Volatile
Organic by GC/MS |
8260A |
| Extraction/Volatiles
(ZHE) |
1311 |
| Extraction/Metals,
Semi-Volatiles, Pesticides, Herbicides |
1311 |
|
|
| Ignitibility |
|
| P-M Closed Cup |
1010 |
|
|
| Corrosivity |
|
| pH |
9045C |
|
|
| Reactivity |
|
| Quantification
of Free sulfide |
SW 846
protocol |
| Quantification
of Free cyanide |
SW 846
protocol |
|
|
| Other |
|
| Paint
Filter Liquid |
9095 |
| Total
Organic Halide |
9020B |
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Organic
Compounds
|
| The following
analytical methods, described in the FEDERAL REGISTER and SW-846, will
be utilized for analysis of specific organic compounds. |
| |
|
| GC/MS |
|
| Solid/Waste |
|
|
|
| Semi-Volatile
Organics |
625/8270B |
| Volatile
Organics |
624/8260A |
|
|
| GC |
|
| Acrolein/Acrylonitrile |
603/8030 |
| Alcohols |
8015 |
| Aromatics,
Purgeable |
602/8020A |
| Benzidines |
605/8060 |
| BTEX Only |
602/8020 |
| Chlorinated
Hydrocarbons |
612/8121 |
| Halocarbons,
Purgeable |
601/8010B |
| Haloethers |
611 |
| Herbicides,
Chlorinated |
8151 |
| Nitroaromatics/Isophorone |
609/8090 |
| Nitrosoamines |
607 |
| PCB |
608/8081 |
| PCB in
Oil |
EPA Publication |
| Pesticides
and PCB's |
608/8081 |
| Pesticides,
Chlorinated |
608/8081 |
| Pesticides,
Organophosphorus |
8141 |
| Phenols |
604/8040 |
| Phthalate
Esters |
606/8060 |
| Polynuclear
Aromatic Hydrocarbons (PAH) |
610/8100 |
| TPH/Gasoline |
8015M |
| TPH Diesel |
8015 M |
|
|
| HPLC |
|
|
|
| Aldehydes
|
8315 |
| Polynuclear
Aromatic Hydrocarbons (PAH) |
8310 |
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Soil/Sediment/29B
|
The following
test methods are utilized for the analysis of soil and sediment samples
according to procedures described in "Test Methods for the Evaluation
of Solid Waste," 1994 (SW-846), Louisiana Statewide Order 29B, "Methods
of Soil Analysis", 1982. Procedures follow US EPA "Procedure
for handling and chemical analysis of sediment and water samples"
1981.
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|
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ANALYSIS
|
METHOD
|
|
|
| Ammonia
Nitrogen |
350.2M |
| Barium
(29B only) |
LADNR-29B |
| BTEX (PID) |
8260/8020 |
| Bromide
(Titrimetric) |
320.1M |
| Cation
Exchange Capacity (CEC) |
9080/9081 |
| Chloride,
Leachable |
LaDNR-29B |
| Chloride
(Titrimetric) |
9252A |
| Conductivity
(Specific Conductance) |
9050 |
| Cyanide,
Total (Spectrophotometric) |
9010A |
| Exchangeable
Sodium Percentage (ESP) |
LaDNR-29B |
| Exchangeable
Organic Halide (EOX) |
EPA600/4/84-008 |
| Fluoride
(Potentiometric) |
340.2M |
| Iodine
(Titrimetric) |
345.1M |
| Mercury |
7471A |
| Metals
(ICP) |
6010A |
| Metals
Prep |
3050A/3051 |
| Moisture
% |
D1037 |
| Nitrate/Nitrite |
353.3M |
| Nitrogen,
TKN |
350.3M |
| Oil and
Grease/Chloride, Leachable |
LaDNR-29B |
| Oil and
Grease, Leachable |
LaDNR-29B |
| Oil and
Grease, Total Recoverable |
9071A |
| pH (Electrometric) |
9045C |
| Phenols,
Total Recoverable |
9065 |
| Phosphorus,
all forms |
6010A
|
| Sodium
Absorption Ratio (SAR) |
LaDNR-29B |
| Solids,
Total |
2540G |
| Sulfates |
9038 |
| Total
Petroleum Hydrocarbons (Soxlet) |
5520F |
| Total
Petroleum Hydrocarbons-Diesel (GC/FID) |
CaDHHR |
| Total
Petroleum Hydrocarbons-Gas (GC-FID) |
CaDHHR |
|
|
All other
analytical methods employed will be based on the most recently promulgated
methods in the FEDERAL REGISTER.
NOTE: Method numbers followed by "M" indicate EPA water methods
that have been modified to accomodate a soil preparation step.
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Speciality
Analysis/Miscellaneous Methods
|
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ANALYSIS
|
METHOD
|
|
|
| Acid Percent |
FCCIII
Monograph |
| Ash |
ASTM D482 |
| BTU, Heat
of Combustion |
ASTM D240 |
| Caustic
Percent |
FCC III
Monograph |
| Chloride/Sulfur
(Parr Bomb) |
ASTM D808
& D129 |
| Flash
Point |
ASTM D92,
D93 |
| Formaldehyde
in Water |
FCC III
Monograph |
| Halogens
(Microculombric) |
Dohrmann
Method |
| Halogens
(Parr Bomb) |
ASTM D808 |
| Heavy
Metals (as Lead) |
FCC III
Monograph |
| Hydroxyl
Number |
ASTM D1638 |
| Metals
in Oil |
ASTM D2788,
D811 |
| pH (Extract) |
ASTM D2110 |
| Saponification
No. |
ASTM D94 |
| Specific
Gravity/Density |
ASTM D891,
D1298 |
| Sulfur
(Parr Bomb) |
ASTM D129 |
| Miscellaneous
ASTM/Food Chemical |
Codex
(FCC) |
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